Abstract
Fe–Ni nano-alloy which was prepared by chemical reduction with KBH 4 as reductant and polyethylene glycol (PEG) as dispersant had high surface energy after being deoxidized in H 2 atmosphere at 400 °C. It could cause breakage of C–Cl bond of organic chloride in the presence of a small amount of oxygen. The result of elemental analysis indicated that the reaction products were FeCl 2, NiCl 2 and Cl 2, the production of Cl 2 was because of the combination of Cl atom or Cl free radical that came from the breakage of C–Cl bond. High-performance liquid chromatography (HPLC) result showed that the existence of new organic compound such as biphenyl and so on. The results of X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) showed that carbon free radical or carbonaceous free radical enchased on the surface of nano-alloy and produced Fe 3C, Fe 2C after being baked in N 2 atmosphere at 600 °C.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
