Abstract
To better understand the thermodynamic behaviour of chlorine in blast furnaces, CaO‐SiO2‐Al2O3 slags were brought into equilibrium with Ar + H2 + HCl + H2O gas mixtures at temperatures between 1673 K and 1798 K. The dissolution of chlorine into molten slags could be well interpreted through a reaction: (1/2) {CaO}slag + (HCl) = {Ca1/2Cl}slag + (1/2) (H2O). Conforming to this formula, a linear relation was observed between log (%CI) and log with an anticipated slope of 1/2.
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