Re-Evaluation of the UK's HFC-134a Emissions Inventory Based on Atmospheric Observations.

Daniel Say,Matt Rigby,Alistair J Manning,Dickon Young,Aoife Grant,Simon O’Doherty

doi:10.1021/acs.est.6b03630

Daniel Say, Matt Rigby + Show 4 more

Open Access

https://doi.org/10.1021/acs.est.6b03630

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Abstract

Independent verification of national greenhouse gas inventories is a vital measure for cross-checking the accuracy of emissions data submitted to the United Nations Framework Convention on Climate Change (UNFCCC). We infer annual UK emissions of HFC-134a from 1995 to 2012 using atmospheric observations and an inverse modeling technique, and compare with the UK's annual UNFCCC submission. By 2010, the inventory is almost twice as large as our estimates, with an "emissions gap" equating to 3.90 (3.20-4.30) Tg CO2e. We evaluate the RAC (Refrigeration and Air-Conditioning) model, a bottom up model used to quantify UK emissions from refrigeration and air-conditioning sectors. Within mobile air-conditioning (MAC), the largest RAC sector and most significant UK source (59%), we find a number of assumptions that may be considered oversimplistic and conservative; most notably the unit refill rate. Finally, a Bayesian approach is used to estimate probable inventory inputs required for minimization of the emissions discrepancy. Our top-down estimates provide only a weak constraint on inventory model parameters and consequently, we are unable to suggest discrete values. However, a significant revision of the MAC servicing rate, coupled with a reassessment of non-RAC aerosol emissions, are required if the discrepancy between methods is to be reduced.

Highlights

As a result of the Montreal Protocol on Substances that Deplete the Ozone Layer and subsequent amendments,[1−3] the production and consumption of ozone-depleting chlorofluorocarbons (CFCs), and their interim replacements hydrofluorochlorocarbons (HCFCs), is prohibited in Annex 1 nations for all dispersive nonessential use
Within mobile air-conditioning (MAC), the largest Refrigeration and Air-Conditioning (RAC) sector and most significant UK source (59%), we find a number of assumptions that may be considered oversimplistic and conservative; most notably the unit refill rate
HFCs were included within the Kyoto basket of greenhouse gases (GHGs), defined as one of six key groups of species deemed to have an adverse effect on global climate

Summary

Introduction

As a result of the Montreal Protocol on Substances that Deplete the Ozone Layer and subsequent amendments,[1−3] the production and consumption of ozone-depleting chlorofluorocarbons (CFCs), and their interim replacements hydrofluorochlorocarbons (HCFCs), is prohibited in Annex 1 nations for all dispersive nonessential use. Within mobile air-conditioning (MAC), the largest RAC sector and most significant UK source (59%), we find a number of assumptions that may be considered oversimplistic and conservative; most notably the unit refill rate. The complex nature of each refrigeration sector results in a number of assumptions being made, including unit lifetime and service rate, all of which increase the uncertainty of the final estimate.

Results

Conclusion