Abstract

Quantitative CN, OH, and OH rotational temperature, and velocity two-dimensional profiles have been imaged using planar laser-induced fluorescence (PLIF) imaging or particle-imaging velocimetry (PIV) during ignition and deradiative extinguishment of cyclotrimethylene-trimitramine, (RDX) at three different heat flux levels. Relative NO2 and NO profiles were also imaged with PLIF. Decomposition products, such as NO and NO2 were formed early in the laser heating process and the gas plume moved, away from the surface. At a later time, ignition occurred in the gas phase, as evidenced by radical buildup such as CN and OH. This often showed as a spherical ignition kernel away from the surface. The flame then transitioned rapidly to a thin flame sheet that moved toward the surface. With longer heating times, laser-supported quasi-steady-state-deflagration develops as the flame sheet again moves somewhat further from the surface. This data can be used as an aide in the development of fully time-dependent RDX combustion models. The ignition and deradiative extinguishment data will help validate these time-accurate models, which can then be used to study combustion instability.

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