Rationally Designed Functional Ni2P Nanoparticles as Co–Catalyst Modified CdS@g‐C3N4 Heterojunction for Efficient Photocatalytic Hydrogen Evolution

Abstract

AbstractNi2P nanoparticle contained no precious metal as co‐catalyst to touch up CdS nanorods coupling with graphitic C3N4 for H2 evolution was synthesized successfully by in‐situ fabrication approach. The preparative Ni2P‐CdS/g‐C3N4 composite catalyst exerts remarkable hydrogen production activity and exhibit good photostability in 20 hour cycles. The hydrogen evolution rate is 9.9 times as high as that of pure CdS. Morphological characterization, optical results and electrochemical test proved that special CdS/g‐C3N4 enhanced the transfer of electrons on CdS and g‐C3N4, loading Ni2P co‐catalyst further increased the synergistic effect in photocatalytic properties. Several characterization results such as transmission electron microscopy (TEM), X‐ray diffraction (XRD), The Ultraviolet–visible spectroscopy diffuse reflectance spectroscopy (UV‐vis DRS), Photoluminescence (PL) and nitrogen adsorption‐desorption isotherms (BET) etc. indicate that the Ni2P nanoparticles loaded on the CdS/g‐C3N4 exposed more active sites and facilitated the efficiency of photogenic electron‐hole pairs separation. Optimistically, these results were good consistent with each other. This considerable performance probablely attribute to the special conduction band (CB) and valence band (VB) of CdS and g‐C3N4 which form a heterojuction and the introduction of Ni2P as cocatalyst further extract photogenerated electrons that lower the over potential of H+ redution.