Rational design of two-dimensional covalent tilings using a C6-symmetric building block via on-surface Schiff base reaction.

Abstract

Three types of well-ordered covalent two-dimensional tilings including triangular, rhombille and semi-regular Archimedean tilings were successfully constructed via on-surface Schiff base reaction. Among them, the covalent organic framework (COF) constructed from a C6 symmetry monomer and C3 symmetry monomer is the first reported COF with kgd (rhombille tiling) topology.