Rational design of Ni-MoO3–x catalyst towards efficient hydrodeoxygenation of lignin-derived bio-oil into naphthenes

Abstract

Design of a robust catalyst with high activity but the low cost for the hydrodeoxygenation (HDO) of bio-oils is of great importance to bring the biorefinery concept into reality. In this study, density functional theory (DFT) calculation was adopted to analyze the optimal location of Ni on MoO3–x containing oxygen vacancy, and the corresponding result demonstrated that metallic Ni cluster located at the neighborhood of oxygen vacancies would significantly evoke HDO activity. Enlightened by DFT results, NiMoO4 was first hydrothermally synthesized and then employed to fabricate Ni-MoO3–x catalyst via a low-temperature reduction, where Ni escaped from NiMoO4 and was reduced to its metallic state. Such an evolution of Ni species also induced the formation of oxygen vacancies around metallic Ni cluster. In the HDO of p-cresol, Ni-MoO3–x exhibited high activity with a complete conversion and a methylcyclohexane selectivity of 99.4% at 150 °C. Moreover, the catalyst showed good versatility in catalyzing HDO of diverse lignin-derived oxygenates and lignin oil. 2D HSQC NMR, gas chromatograph and elemental analysis of the lignin oil demonstrated the high deoxygenation efficiency and saturation of the benzene ring over Ni-MoO3–x. In the upgrading of crude lignin oil, the deoxygenation degree was up to 99%, and the overall carbon yield of the naphthenes was as high as 69.4%. Importantly, the structures and carbon numbers of the naphthene products are similar to jet fuel-range cycloalkanes, which are expected to have a high density that can be blended into jet fuel to raise the range (or payload) of airplanes. This work demonstrates the feasibility for improving the targeted catalytic reactivity by rational tailoring the catalyst structure under the guidance of theoretical analysis, and provides an energy-efficient route for the upgrading of lignin crude oil into valuable naphthenes.