Rational Design of Mesoporous Silica (SBA-15)/PF (Phenolic Resin) Nanocomposites by Tuning the Pore Sizes of Mesoporous Silica.

Abstract

The development of composite materials with functional additives proved to be an effective way to improve or supplement the required properties of polymers. Herein, mesoporous silica (SBA-15) with different pore sizes were used as functional additives to prepare SBA-15/PF (phenolic resin) nanocomposites, which were prepared by in situ polymerization and then, compression molding. The physical properties and structural parameters of SBA-15 with different pore sizes were characterized by N2 adsorption-desorption, X-ray diffraction (XRD), and scanning electron microscopy (SEM). The thermal properties of the SBA-15/PF hybrid were investigated by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The mechanical, friction, and dynamic mechanical properties of SBA-15/PF nanocomposites were also studied. The results revealed that the pore sizes of SBA-15 have a significant effect on the resulting SBA-15/PF hybrid and SBA-15/PF nanocomposites. The thermal stability of the SBA-15/PF hybrid was dramatically improved in comparison with pure PF. The friction and dynamic mechanical properties of the SBA-15/PF nanocomposites were enhanced significantly. Specifically, the glass transition temperature (Tg) of the nanocomposite increased by 19.0 °C for the SBA-15/PF nanocomposites modified with SBA-15-3. In addition, the nanocomposite exhibited a more stable friction coefficient and a lower wear rate at a high temperature. The enhancement in thermal and frictional properties for the nanocomposites is ascribed to the confinement of the PF chains or chain segments in the mesopores channels.