Rational Design of Chrysene-Based Hybridized Local and Charge-Transfer Molecules as Efficient Non-Doped Deep-Blue Emitters for Simple-Structured Electroluminescent Devices.

Abstract

Herein, we present a molecular design of chrysene-based deep-blue emissive materials (TC, TpPC, TpXC, and TmPC), in which chrysene as a core is functionalized with different triphenylamine moieties to realize a fine-tuning deep-blue fluorescence with superior electroluminescent (EL) performance. The photophysical analyses and density functional theory (DFT) calculations disclose that TC, TpPC, and TpXC possess HLCT characteristics with intense deep-blue emission in the solid-state, good hole-transporting ability, and high thermal and electrochemical stabilities. They are successfully employed as non-doped emitters in simple structured OLEDs (ITO/PEDOT : PSS : NF/emitter/TPBi/LiF : Al). In particular, TC-based device emits a deep-blue light with an emission peak at 446 nm and CIE color coordinates of (0.148, 0.096), a maximum external quantum efficiency (EQEmax ) of 4.31%, and a low turn-on voltage of 2.8 V.