Rational Design of a Polyimide Cathode for a Stable and High-Rate Potassium-Ion Battery.

Abstract

Potassium has similar chemical characteristics compared with lithium while it is more abundant and of low cost, resulting in widespread research attention on potassium-ion batteries (PIBs). Developing organic polymer cathodes has garnered extensive attention because of their merits of environmental friendship and structure diversity, while confronted with inferior cycle stability and low rate performance. In this paper, we utilize the low-cost graphite nanosheets to stabilize polyimide (PI@G) for PIBs. Additionally, the potassium storage mechanism of PI@G was further evaluated; the highly reversible chemical bonds (C═O) of PI@G are responsible to its long-term stability. Consequently, the PI@G exhibits a maximal capacity of 142 mA h g-1 at the current density of 100 mA g-1 and maintains a capacity of 118 mA h g-1 after 500 cycles (corresponding to a capacity fade of 0.034% per cycle). Moreover, the full battery based on the PI@G cathode also reveals promisingly electrochemical performance. This study may have great significance to the application prospect of the organic cathode for PIBs.