Abstract
Rate constants of radiationless electronic transitions in a diatomic molecule in a crystal at non-zero temperature are calculated. The electronic terms of the molecule are simulated by the Morse potential. The crystal vibrations are assumed to be harmonic. The calculations are done under the assumption that perturbation theory is applicable to the operator inducing the electronic transitions. The vibrational interaction of the molecule with the medium is not supposed to be small. The results explain certain experimental data on the radiationless electronic transitions in aromatic hydrocarbons.
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