Abstract
The rates of complex formation for poly-N-vinyl carbazole and its saturated monomer analogue, N-ethyl carbazole, with various electron acceptors (chloranil, trinitrobenzene and picric acid) have been investigated. In mole ratios 1:1, the complex forming reactions in chloroform proceed rapidly, as measured by a “stopped flow” method; the rate constants are of the order of 10 3 1. mole −1 sec −1. The rate constants are smaller than those of the complexes with tetracyanoethylene as acceptor and decrease with decreasing electron affinity of the acceptor. The rate constants also depend on the molecular weight of the donor.
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