Abstract
Rates of gas-solid reactions of the type A gas + B solid → C solid are followed under conditions of pulsed gas-chromatography. The special case is considered wherein B is a non-stoichiometric (“reduced”) oxide and A is oxygen. A generalized method is developed, which implies the selection of a particular dimensionless time. Plots of α, fraction of reduced B which undergoes reoxidation, as a funktion of time will allow to distinguish amongst possible reaction mechanisms. The effects of temperature, particle size, gaseous concentration on the controlling reaction mechanisms has been evaluated over a number of oxides.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
