Rate-dependent damage and failure behavior of lithium-ion battery electrodes

Abstract

The mechanical properties and failure behavior of composite electrodes are critical to understanding the internal short circuits and ensuring the crush safety of lithium-ion batteries used in electric transportation. This study provides a comprehensive experimental investigation into the strain rate–dependent tensile/compressive behavior and failure mechanism of both anode and cathode, covering a range from quasi-static to dynamic conditions. A universal testing machine equipped with an industrial camera was used to assess the mechanical properties and observe the deformation process of the electrodes under quasi-static conditions. Additionally, a split Hopkinson bar system, coupled with a high-speed camera, was utilized to evaluate the mechanical properties and capture the deformation process of the electrodes under dynamic loading. The detailed deformation and failure modes of the electrodes were revealed by a combination of post-mortem characterization and images from high-speed cameras. The experimental results demonstrate a significant strain rate effect on the tensile and compressive mechanical behavior and failure mechanism of both anode and cathode. The rate dependence of tensile/compressive strength and failure strain were discussed, and the underlying mechanism for strain rate sensitivity was analyzed. The results and conclusions from this study provide an important foundation for the detailed modeling and failure prediction of lithium-ion batteries under impact loading. Further, these findings facilitate the safety design of electric vehicles by informing to enhance crash safety.