Abstract
With the use of kinetic models for a photodissociation iodine laser the calculation of the effective rate constants for chemical reactions in a gaseous active mixture is carried out in the case of a strong influence of molecular collisions. The analysis uses a detailed reaction scheme and Lindemann's collisional mechanism. A list of measured values of rate constants for all reactions occurring in the photodissociation iodine laser active volume for the most important perfluorocarbon radicals is attached.
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