Rate Constants and Mechanisms for Reactions of Bromine Radicals with Trace Organic Contaminants.

Abstract

Bromine radicals can pose great impacts on the photochemical transformation of trace organic contaminants in natural and engineered waters. However, the reaction kinetics and mechanisms involved are barely known. In this work, second-order reaction rate constants with Br• and Br2•- were determined for 70 common trace organic contaminants and for 17 model compounds using laser flash photolysis and steady-state competition kinetics. The kBr• values ranged from <108 to (2.86 ± 0.31) × 1010 M-1 s-1 and the kBr2•- values from <105 to (1.18 ± 0.09) × 109 M-1 s-1 at pH 7.0. Six quantitative structure-activity relationships were developed, which allow predicting additional unknown kBr• and kBr2•- values. Single-electron transfer was shown to be a favored pathway for the reactions of Br• and Br2•- with trace organic contaminants, and this was supported by transient spectroscopy and quantum chemical calculations. This study is essential in advancing the scientific understanding of halogen radical-involved chemistry in contaminant transformation.