Abstract
Rate coefficients for the reactions of cyclohexadienyl ( c-C 6H 7) radicals with O 2 and NO were measured at 296 ± 2 K. The c-C 6H 7 radicals were detected selectively by laser-induced fluorescence. The rate coefficient for the reaction of c-C 6H 7 with O 2, (4.4 ± 0.5) × 10 −14 cm 3 molecule −1 s −1, was independent of the bath-gas (He) pressure (13–80 Torr). In the reaction of c-C 6H 7 with NO, thermal equilibrium among c-C 6H 7, NO, and C 6H 7NO was observed. The forward and reverse reactions were in the falloff region, and the equilibrium constant was (1.5 ± 0.6) × 10 −15 cm 3 molecule −1.
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