Abstract

Rasta resin-TBD (RR-TBD) was found to be an efficient organocatalyst for γ-selective Morita–Baylis–Hillman reactions between α,γ-disubstituted allenones and aryl aldehydes. In these reactions the heterogeneous nature of RR-TBD greatly facilitated product isolation since the catalyst could be separated simply by filtration.

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