Abstract

Cerium oxide (CeO2) in the range of 0–16 mol.% is used to enhance the joint of Ag-based filler for brazing yttria-stabilized zirconia (YSZ) ceramic in the air. Ag–CeO2 filler is first adopted to braze YSZ ceramic (3 mol.% yttria). The CeO2 is found to cluster at the interface of YSZ and Ag seam, improving the wetting behavior of Ag-based fillers. The maximum shear strength of YSZ joints can reach 35.1 MPa using Ag–1CeO2 fillers at 1050 °C/30 min. Moreover, CeO2 is used to enhance the Ag–CuO filler for brazing YSZ ceramic. As the increase of CeO2 content, the contact angle of Ag–CuO on the YSZ surface decreases first and then increases. The average shear strength could reach 76.5 MPa using Ag–CuO–8CeO2 at 1050 °C/30 min. The CeO2 could decrease residual stress by adjusting the linear expansion coefficient of Ag-based fillers. Therefore, this study provides a new strategy for exploring air brazing fillers.

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