Rare Earth Iodide Complexes of 4-Formyl-2, 3-Dimethyl-l-Phenyl-3-Pyrazolin-5-One

Abstract

Rare earth complexes of 4-lbrmyl-2, 3-dimethyl-l-phenyl-3-pyrazolin-5-onc (FDPP) having the general formula [Ln(FDPP)4I2]I, where Ln = Y. La, Pi, Nd. Sm, Eu, Gd, Dy, Ho and Er, have been synthesised and characterised by elemental analyses, molar conductance in non-aqueous solvents, electronic, infrared and proton NMR spectra as well as thermogravimetric analyses. FDPP acts as a neutral monodentate ligand coordinating through the ring carbonyl oxygen. Two of the iodide ions are coordinated. A coordination number of six may be assigned to the metal ion in these complexes. The covalency parameters evaluated from the solid state electronic spectra suggest weak covalent character of the metal-ligand bond. The TG data of the lanthanum complex indicate that the complex is stable up to about 140°C and undergoes decomposition in three stages forming lanthanum oxide as the final product.