Rare earth-based halide double perovskite phosphor Cs2NaScCl6: Yb3+, Er3+ for multi-mode anti-counterfeiting application

Abstract

At present, most fluorescent anti-counterfeiting technologies on the market are based on single-mode luminescence, which generally have poor anti-counterfeiting capabilities. Thus, developing multi-mode luminescent anti-counterfeiting materials that combine dynamic and static luminescence is a particularly urgent task. In this study, Cs2NaScCl6: Yb3+, Er3+phosphors were successfully prepared using the solvothermal method. These materials can emit bright green light under 980- or 1550-nm infrared laser irradiation and red light under 365-nm ultraviolet lamp illumination. In addition, by increasing the 980-nm laser power density from 20 to 309 mW/cm2, the luminescence colour can be adjusted from green to yellow, which equips this sample with an outstanding potential for dynamic anti-counterfeiting. Finally, screen printing technology was used to assess the sample's anti-counterfeiting capacity, and the sample was found to be an excellent anti-counterfeiting luminescent material.