Rapid separation and purification of uranium and plutonium from dilute-matrix samples

Abstract

This work describes a streamlined approach to the separation and purification of trace uranium and plutonium in environmental swipe samples that contain a small amount of collected bulk material. We describe key modifications to conventional techniques that result in a relatively rapid, safe, cost-effective, and efficient U and Pu separation process. Simulated samples were produced by loading appropriate 235U, 238U, and 240Pu onto high purity cotton swipes. Uranium concentration and isotopic composition were measured by multi-collector inductively coupled mass spectrometry. Corresponding plutonium measurements were conducted with a three stage thermal ionization mass spectrometer. Quantitative U and Pu recoveries were observed with this method.