Rapid Separation and Efficient Removal of Cd Based on Enhancing Surface Precipitation by Carbonate-Modified Biochar.

Abstract

The high buoyancy of biochar makes its application difficult in Cd removal. In this paper, the content of minerals was increased by modifying carbonate on the biochar surface using the vacuum impregnation method. Enhancing surface precipitation between minerals and Cd introduced a correspondingly great number of Cd precipitates on the biochar surface, leading to the rapid precipitation and separation of buoyant biochar. The physical and chemical properties of carbonate-modified biochar and the adsorption mechanism of Cd were comprehensively studied by jar tests, scanning electron microscopy–energy-dispersive X-ray spectroscopy, X-ray diffraction, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. The results showed that the adsorption of Cd by carbonate-modified biochar was controlled by multiple mechanisms, including surface precipitation, surface complexation, and Cd−π interaction. Surface precipitation dominated the removal of Cd. The contributions of Cd removal mechanisms indicated that the contribution proportions of minerals increased from 89.73 to 97.9% when the pyrolysis temperature increased from 300 to 600 °C, while the contribution proportions of Cd−π binding decreased from 9.99 to 2.08%. Meanwhile, oxygen functional groups have only a marginal effect on Cd adsorption. Besides, the results revealed that the higher surface hydrophobicity and the lower polarity were conducive to biochar separation from water. The Cd removal method can provide efficient adsorption and rapid separation, making it possible to use biochar in water treatment.