Rapid laser reactive sintering of BaCe0.7Zr0.1Y0.1Yb0.1O3-δ electrolyte for protonic ceramic fuel cells

Abstract

The state-of-the-art protonic ceramic electrolyte BaCe 0.7 Zr 0.1 Y 0.1 Yb 0.1 O 3-δ (BCZYYb) dense films were successfully deposited on the pre-sintered Ni(O)+BCZYYb anode substrate by recently developed rapid laser reactive sintering (RLRS) method. The separation of the deposition of dense electrolyte from the preparation of porous anode makes it possible to manufacture protonic ceramic fuel cells (PCFCs) with more desirable electrolyte and anode microstructures. The PCFC single cells prepared after introducing the cathode thin film BaCo 0.4 Fe 0.4 Zr 0.1 Y 0.1 O 3-δ (BCFZY0.1) showed OCVs of 0.94–0.97V and peak power densities of 97 mW/cm 2 at 600 °C and 121 mW/cm 2 at 600–650 °C under Air/H 2 gradient. The proton conductivity of the BCZYYb film derived the RLRS-derived single cell showed a moderate proton conductivity of 3.7 × 10 −3 S/cm at 600 °C. The higher PCFC performance can be expected by further optimization of the thickness, compositions, and/or microstructures of the component layers. Rapid laser reactive sintering deposited a dense BCZYYb electrolyte on a pre-sintered BCZYYb ​+ ​Ni(O) anode, which allowed the independent fabrication of each component layer for PCFCs to achieve desired structures for high performance. • Rapid laser reactive sintering (RLRS) can make dense electrolyte on sintered anode. • RLRS-derived electrolyte shows a moderate proton conductivity. • RLRS can provide knowledge to the rapid additive manufacturing of ceramics. • RLRS allows independent control of microstructures of fuel cell component layers.