Abstract

Nanosized ZSM-22 with high crystallinity was synthesized rapidly by a high-temperature hydrothermal synthesis method. The effects of synthesis conditions such as crystallization temperature, crystallization time, Si/Al ratios and crystallinity of ZSM-22 were investigated, and the relationship between crystallization temperature and crystallization time was calculated by Arrhenius equation. Meanwhile, the rapid high-temperature synthesis method was effective to synthesize ZSM-22 with Si/Al ratio from 35 to 70. The nanosized ZSM-22 exhibited high light olefin selectivity and a long lifetime in the MTO reaction.

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