Abstract
Porous carbon nanosheets (PCNs) with a large two-dimensional morphology and high porosity have emerged as an important class of 2D materials, while developing novel technology to manufacture high-quality PCNs in terms of convenience, high output, and economic benefit remains a challenge. Herein, a rapid gas-engineering technology is developed to fabricate graphene-like mesoporous carbon nanosheets (MCNs) with large aspect ratios (>2500, length/thickness). By easy carbonization of calcium gluconate under reduced pressure, MCNs with ultrathin (∼12 nm) thickness, ultralarge (>20 μm) lamella morphology, and high surface area (∼1155 m2/g) are fabricated in kilogram scale. Two-dimensional lamella morphology transformation, pore architectures, and calcium compounds transformation mechanisms are unraveled by in situ variable temperature X-ray diffraction (VT-XRD), high-resolution transmission electron microscopy (HRTEM), ex situ scanning electron microscopy (SEM), and atomic force microscopy (AFM). The key to the synthesis is the negative pressure operation, which triggers the rapid gas expansion in a gas-solid system. This design relied on the gas expansion mechanism has realized producing of high-quality MCNs via a rapid, high-throughput, and cost-effective way. Due to high surface utilization and low weight density, when served as a lightweight separator coating layer, MCNs exhibit impressive capture ability toward polysulfides and achieve a high-stability lithium-sulfur battery.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.