Rapid determination of moisture content of multi-source solid waste using ATR-FTIR and multiple machine learning methods

Abstract

Rapid determination of moisture content plays an important role in guiding the recycling, treatment and disposal of solid waste, as the moisture content of solid waste directly affects the leachate generation, microbial activities, pollutants leaching and energy consumption during thermal treatment. Traditional moisture content measurement methods are time-consuming, cumbersome and destructive to samples. Therefore, a rapid and nondestructive method for determining the moisture content of solid waste has become a key technology. In this work, an attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR) and multiple machine learning methods was developed to predict the moisture content of multi-source solid waste (textile, paper, leather and wood waste). A combined model was proposed for moisture content regression prediction, and the applicability of 20 combinations of five spectral preprocessing methods and four regression algorithms were discussed to further improve the modeling accuracy. Furthermore, the prediction result based on the water-band spectra was compared with the prediction result based on the full-band spectra. The result showed that the combination model can efficiently predict the moisture content of multi-source solid waste, and the R2 values of the validation and test datasets and the root mean square error for the moisture prediction reached 0.9604, 0.9660, and 3.80, respectively after the hyperparameter optimization. The excellent performance indicated that the proposed combined models can rapidly and accurately measure the moisture content of solid waste, which is significant for the existing waste characterization scheme, and for the further real-time monitoring and management of solid waste treatment and disposal process.