Abstract
However, they often suffer from serious disadvantages, suchas functional group incompatibility, difficult work-up proce-dures, harsh reaction conditions, or not readily availablereagents. Further some of these methods are associated withlimitations regarding low yields and prolonged reactiontimes. Therefore, the search for a new and efficient methodfor the deoxygenation of sulfoxides is still a worthwhilegoal. Particularly much effort has been devoted to thedevelopment of milder conditions where the presence ofvarious sensitive and reducible functional groups can betolerated. The use of low valent oxophilic d-block metals(Zr, Ti, W, Mo) have become important in deoxygenation ofvarious types of organic substrates.
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