Abstract

A considerable number of systems have recently been reported in which Brownian yet non-Gaussian dynamics was observed. These are processes characterised by a linear growth in time of the mean squared displacement, yet the probability density function of the particle displacement is distinctly non-Gaussian, and often of exponential (Laplace) shape. This apparently ubiquitous behaviour observed in very different physical systems has been interpreted as resulting from diffusion in inhomogeneous environments and mathematically represented through a variable, stochastic diffusion coefficient. Indeed different models describing a fluctuating diffusivity have been studied. Here we present a new view of the stochastic basis describing time-dependent random diffusivities within a broad spectrum of distributions. Concretely, our study is based on the very generic class of the generalised Gamma distribution. Two models for the particle spreading in such random diffusivity settings are studied. The first belongs to the class of generalised grey Brownian motion while the second follows from the idea of diffusing diffusivities. The two processes exhibit significant characteristics which reproduce experimental results from different biological and physical systems. We promote these two physical models for the description of stochastic particle motion in complex environments.

Highlights

  • The systematic study of the diffusive motion of tracer particles in fluids dates back to the 19th century, referring to Robert Brown’s experiments observing the erratic motion of granules extracted from pollen grains which were suspended in water [1]

  • Experiments have demonstrated that a non-Gaussian dynamic may persist throughout the observation window and that there are systems that, instead, at long time (LT), exhibit a crossover to Gaussian diffusion

  • In this article we introduced an analytic approach to generate a random and time-dependent diffusivity with specific features and we proposed two possible models for the spreading dynamics of particles in complex systems: one belonging to the class of generalised grey Brownian motion (ggBM) and the other supporting the idea of diffusing diffusivities (DD)

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Summary

25 April 2018

Vittoria Sposini, Aleksei V Chechkin, Flavio Seno, Gianni Pagnini and Ralf Metzler.

Introduction
Generalised grey Brownian motion with random diffusivity
Diffusing diffusivity: stochastic equations for random diffusivity
A generalised minimal model for DD
Long time regime
Non-equilibrium initial conditions
Conclusions
Computation via Fox H-function
Asymptotic trend via Laplace method
Full Text
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