Abstract
AbstractThe Raman and infrared spectra of 13C‐substituted poly‐p‐phenylene (PPP) and the Raman spectra of Na‐doped PPP excited at 488.0 and 1064 nm were observed and compared with the corresponding spectra for the ordinary (12C) polymer. 13C substitution is shown to be useful for characterizing not only the bands of intact PPP but also those of polarons and bipolarons generated in Na‐doped PPP. The number of Raman bands observed for bioplarons (and also for polarons) is greater than that for intact PPP. This observation is explained as the result of the loss of translational symmetry in the regions of these local excitations.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
