Abstract
The superionic phase transition of Cs3D(SO4)2 (TCDS) is investigated using Raman scattering and differential scanning calorimetry (DSC) measurements. It is confirmed that TCDS undergoes a superionic phase transition at 415.1 K. The result of the Raman scattering measurement at room temperature shows that TCDS does not form the dimer structure SO4⋯D⋯SO4. It suggests that this phase transition is not caused by the destruction of hydrogen bonds forming a dimer structure.
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