Abstract

Electrochemical nanostructuring of ordered C60 fullerene layers in aqueous solution was studied by in situ Raman spectroelectrochemistry. A completely changed molecular film structure was found for nanostructured films. C60 polymers/oligomers and hydrogenated C60 were identified as the main fullerene structures after nanostructuring. No significant contributions of AxC60 fullerides (A=alkaline metal; x=1, 3, 6) were found.

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