Raman spectra of polycrystalline microdiamond inclusions in zircons, and ultrahigh-pressure metamorphism of a quartzofeldspathic rock from the Erzgebirge terrane, Germany

Abstract

ABSTRACTPolycrystalline microdiamonds are rare in ultrahigh-pressure (UHP) rocks worldwide. Among samples collected at Erzgebirge, Germany, we found abundant polycrystalline microdiamonds as inclusions in zircons from a quartzofeldspathic rock. To illuminate their origin and forming age, we investigated morphologies and Raman spectra of 52 microdiamond inclusions, and dated the zircon host. The zircons have low Th/U values (0.03–0.07) and a concordia U/Pb age of 335.8 ± 1.9 Ma. Polycrystalline diamond (10–40 µm) consists of many fine-grained crystals (1.5–3 µm) with different orientations; discrete single diamonds (2–20 µm) are rare. All measured Raman spectra show an intense diamond band at 1332–1328 cm−1 and have a negative correlation with full width at half maximum (FWHM) of 5.8–11.3 cm−1. These data combined with previously reported diamond band data (1331–1337 cm−1) are compatible with those of diamond inclusions in various host minerals from other UHP terranes, but are different from those of ureil...