Abstract
We report a Raman scattering determination of the energy difference EΓ−L between the Γ conduction-band minimum and the L valley minima in n-type Ga1−xInxAsySb1−y lattice matched to GaSb (x=0.15, y=0.13). A frequency downshift in the L+ phonon–plasmon coupled mode is observed between 80 K and room temperature that is attributed to electron transfer from the Γ to the L valleys. We use the L+ frequency shift to evaluate EΓ−L by performing Lindhard–Mermin L+ line-shape fits for different EΓ−L values. The EΓ−L value increases with electron concentration due to band gap renormalization. A value EΓ−L=154 meV is derived for intrinsic material.
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