Abstract
AbstractLinewidths of isotropic and anisotropic Raman bands of the CD stretching mode of chloroform‐d have been measured in ether and in carbon tetrachloride, and the hydrogen bonding between chloroform and ether has been investigated from the analysis of the linewidths. Theoretical Raman linewidths due to vibrational and reorientational relaxation have been calculated for two models. One is a non‐hydrogen‐bonded model where a single chloroform molecule is surrounded by ether molecules without forming hydrogen bonds, and the other is a hydrogen‐bonded model where a chloroform‐ether complex as a solute is surrounded by ether molecules. The concentration dependences of experimental Raman linewidths are discussed in relation to these two models.
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