Abstract

The crevice corrosion occurrence probability of stainless steel (SS) AISI 316 was increased under ennoblement condition due to chemically added H(2)O(2) into seawater. The H(2)O(2) was used to simulate the important factor causing ennoblement in natural marine biofilm. Morphology of the crevice corrosion was observed using an incident-light source microscopy. Some interesting rainbow fringes were observed around micro-crevices. The mechanism was discussed from the ions diffusion and potential distribution during the crevice formation. This result shows that under ennoblement condition the colored fringe is a distinct characteristic of the morphology of localized corrosion for stainless steel.

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