Abstract
SummaryThe use of adamantane matrices for investigating radiolysis processes in biochemically relevant systems is described. Data are given for radiolyses of D-(-)-ribose, D-2-deoxyribose, thymine, and cytosine, and possible radicals formed are discussed. Experimental details and data are given for radiolyses conducted in vacuo, under various gaseous atmospheres (CO, CO2, O2, air, N2O, and SO2), and for samples irradiated in vacuo and then exposed to various atmospheres to investigate the possible binding of small molecules to radical sites.
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