Abstract
We have determined the yields of solvated electrons in water-isopropanol mixtures of various compositions using the nitrate ion as scavenger. The yields calculated from the formation of the nitrite ion and from the diminution of hydrogen are in satisfactory agreement. From the data obtained at high nitrate concentrations, we have concluded that the reactions between radicals in the zones of high ionization density are less important than foreseen by the spur diffusion theory. Calculated “free ion” electron yields confirm Freeman's hypothesis concerning the role of the dielectric constant of the medium.
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