Abstract
Gas-chromatographic behavior of halides of arsenic and phosphorus and isotope exchange reactions among these species were investigated by means of radiotracer techniques. The halides studied in the present work include AsCl3, AsBr3, PBr3,76AsBr3,76AsCl3, and As82Br3. It was demonstrated that the rapid isotope exchange of arsenic and bromine took place in the binary systems: AsBr3−AsCl3 and AsBr3−PBr3, in the course of the gas-chromatographic separation process.
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Schedule a callMore From: Journal of Radioanalytical and Nuclear Chemistry Letters
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