Abstract

The molecular-beam magnetic resonance method has been used to study the Zeeman effect of the rotational states of ${\mathrm{O}}_{2}$. The ratio of the $g$-value of the rotational magnetic moment to that of the electron-spin moment was found to be $\frac{{g}_{K}}{{g}_{S}}=+(6.08\ifmmode\pm\else\textpm\fi{}0.74)\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}5}$. The ratio of the $g$-value of the unpaired-electron spin moments in ${\mathrm{O}}_{2}$ to that of the free-electron spin moment was found to be $\frac{{g}_{S}({\mathrm{O}}_{2})}{{g}_{s}(\mathrm{free})}=1\ensuremath{-}(190\ifmmode\pm\else\textpm\fi{}13)\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}6}$.

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