Abstract
UV-irradiation of a toluene solution of C 60Ph 5Cl leads to the formation of the stable C 60Ph 5 cyclopentadienyl-type fullerenyl radical. Under UV-irradiation of a toluene solution of C 60Ph 5Cl containing Hg[P(O)(OPr i ) 2] 2 (Pr i =CH(CH 3) 2), three isomers of the adducts of phosphoryl radicals with C 60Ph 5Cl are formed. Density functional (DFT) approach with the B3LYP functional was used for estimating of the enthalpies of the formation and hyperfine coupling constants for all possible adducts of phosphoryl radicals with C 60Ph 5Cl. Biradical particles C 60Ph 5[P(O)(OPr i ) 2]– C 60Ph 5[P(O)(OPr i ) 2] with a distance between unpaired electrons of about 10.5 Å, are also obtained.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
