Radical Induced Cyclopropane Fragmentation—H-Abstraction—Cyclization Cascade: Synthesis of Carbocyclic Systems Containing Bridgehead Methyl Groups

Gilles Chambournier,Venkat Krishnamurthy,Viresh H Rawal

doi:10.1016/s0040-4039(97)01450-0

Radical Induced Cyclopropane Fragmentation—H-Abstraction—Cyclization Cascade: Synthesis of Carbocyclic Systems Containing Bridgehead Methyl Groups

Gilles Chambournier, Venkat Krishnamurthy + Show 1 more

https://doi.org/10.1016/s0040-4039(97)01450-0

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Journal: Tetrahedron Letters	Publication Date: Sep 1, 1997
Citations: 10

Affiliation: The Ohio State University

#Bridgehead Methyl #Numerous Natural Products + Show 8 more

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Abstract

The intramolecular hydrogen abstraction by an alkyl radical has been exploited for the first time in a synthetically useful tandem sequence that gives rise to cis-fused bicyclic systems carrying bridgehead methyl groups, a structural feature found in numerous natural products. © 1997 Elsevier Science Ltd.

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