Abstract
Radiationless electronic transitions in polyatomic molecules are studied assuming quasidiscrete vibrational spectra. As is shown, the existence of Fermi resonances in such systems allows one to understand irreversible radiationless transitions in isolated molecules. Applying this approach to a molecule in a condensed host material one manages to understand the causes of the early onset of the temperature dependence in the rate constant for radiationless transitions in a number of aromatic compounds.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
