Radiation-Induced Charge Trapping and Low-Frequency Noise of Graphene Transistors

Abstract

We have performed a detailed evaluation of radiation-induced charge trapping and low-frequency noise for back-gated graphene transistors fabricated on a thermal SiO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> layer, with Al <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> or hexagonal boron nitride passivation over-layers. Irradiation with positive or 0 V back-gate bias leads to negative shifts of the charge neutral point (CNP) of the graphene transistors; irradiation under negative back-gate bias leads to positive CNP shifts. The low-frequency noise increases with irradiation and decreases with 400 K postirradiation annealing. The temperature dependence of the noise is described well by the Dutta-Horn model of low-frequency noise. Peaks in effective defect-energy distributions of irradiated devices at ~0.4 and ~0.7 eV are identified via measurements of the temperature dependence of the low-frequency noise. The noise of as-processed devices stored in room ambient also decreases with baking, but does not show the clear peaks observed after irradiation. Density functional theory calculations suggest that OH <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">-</sup> and H <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">+</sup> at or near the graphene/dielectric interfaces likely play key roles in both the irradiation and baking response. Low-frequency noise and CNP voltage shifts during switched-bias postirradiation annealing at room temperature also suggest significant roles for O vacancies in the near interfacial SiO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> and/or passivation layers.