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Abstract
Trichloronitromethane on exposure to 60Co γ-rays at 77 K gives NO2 radicals by dissociative electron capture. However, in methanol glasses, NO2 is barely detectable, the predominating radical formed by electron capture being ·CCl3. The hole centre formed by this molecule is thought to be CCl3NO+2 with the unpaired electron largely confined to oxygen.
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Schedule a callMore From: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
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