Radial wave functions of a discrete spectrum

Abstract

The system of equations for radial wave functions is written in a form allowing both relativistic and non relativistic wave functions to be obtained. In the case of a discrete spectrum, an asymptotic solution of this system is obtained for a potential which includes not only a Coulomb term but also terms corresponding to dipole and quadrupole polarization. The normalizing factor of the asymptote is determined in the approximation of the relativistic quantum-defect method, which offers the possibility, in principle, of using the functions in semiempirical calculations analogous to nonrelativistic calculations by the Bates — Damgaard — Seaton method. The calculation scheme is illustrated for the example of the calculation of Si IV wave functions.