Abstract

An analysis of the unsteady-state heat-conduction problem in isotachophoretic columns of circular cross-section is given, based on a linear variation of electrica conductivity with temperature and taking into account the effects of a finite wall thickness. It is seen that previous analyses, based on constant electrical conductivity, tend to underpredict actual temperature distributions considerably. The use of thick-walled columns is seen to be advantageous both from the viewpoint of higher resolution and of increased production.

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