Abstract

High compression of sorbent powders promotes flow uniformity and reduces interstitial porosity. These features were exploited in a radial flow configuration to show that good peak resolution was possible for applications to analytical chromatography. An exact analytical solution was uncovered to predict the transient response of an elementary pulse of solute in a flowing inert gas. Experiments on the system methane on alumina are compared quite favorably with theory, showing that the key dissipative force for band broadening is radial diffusion

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