Abstract
The title compound, [Fe2(C5H5)2(C21H21N3O2)], a potential novel N,N′,N′′-tridentate ligand with (non-crystallographic) C 2 axial symmetry, adopts a U-shaped molecular conformation.
Highlights
For the applications of ferrocenes, see: Feng et al (2008)
Ferrocene derivatives have come a long way as a tool in chemistry, with applications in electrochemistry, materials science, synthesis and catalysis (Feng et al, 2008)
The resurgence of interest in 1,2-disubstituted planar-chiral ferrocenes has resulted in numerous interesting compounds which are finding widespread application in asymmetric catalysis (Richards & Locke, 1998; Kagan & Riant, 1997)
Summary
For the applications of ferrocenes, see: Feng et al (2008). For the use of 1,2-disubstituted planar-chiral ferrocenes in asymmetric catalysis, see: Richards & Locke (1998); Kagan & Riant (1997). Absorption correction: multi-scan (SADABS; Blessing, 1995; Sheldrick, 2004) Key indicators: single-crystal X-ray study; T = 298 K; mean (C–C) = 0.011 Å; R factor = 0.098; wR factor = 0.199; data-to-parameter ratio = 14.9. For the use of 1,2-disubstituted planar-chiral ferrocenes in asymmetric catalysis, see: Richards & Locke (1998); Kagan & Riant
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