Quick Heat Dissipation in Absorption-Dominated Microwave Shielding Properties of Flexible Poly(vinylidene fluoride)/Carbon Nanotube/Co Composite Films with Anisotropy-Shaped Co (Flowers or Chains).

Abstract

The facile fabrication of thin flexible electromagnetic interference (EMI) shielding materials with fast heat dissipation for adaptable tuning in both civil and military applications is in urgent demand. In our work, the flexible poly(vinylidene fluoride) (PVDF)/carbon nanotube (CNT) composite films decorated with anisotropy-shaped Co in flowers or chains were prepared and studied. The results showed that by increasing the Co filler contents, the EC (electrical conductivity), TC (thermal conductivity), and EMI shielding properties of such PVDF/CNT/Co (flowers or chains) flexible films were significantly improved. In contrast, the PVDF/CNT/Co-chain flexible films exhibit higher performance with respect to the EC, TC, and EMI shielding properties. Total shielding of 35.3 and 32.2 dB were, respectively, obtained by the PVDF/CNT/6 wt % Co-chain with an EC of 2.28 S/cm and the PVDF/CNT/6 wt % Co-flower with an EC of 1.94 S/cm at a film thickness of 0.3 mm. Possibly owing to the conductive dissipation, interfacial polarization, magnetic loss, multiple reflections, and scattering of EM waves, such flexible composite films possessed a remarkable absorption-dominated EMI shielding behavior. These new composite films with enhanced TC are easily able to transform microwave energy into Joule heating systems, making themselves greatly potential for effective EMI shielding as well as rapid heat dissipation.